Chemical,isotopic and amino acid composition of Mukundpura CM2.0(CM1) chondrite: Evidence of parent body aqueous alteration     

N.G.Rudraswami  A.K.Naik  R.P.Tripathi  N.BhANDari  S.G.Karapurkar  M.Shyam Prasad  E.V.S.S.K.Babu  U.V.R.Vijaya Sarathi 《地学前缘(英文版)》2019,10(2):495-504

The carbonaceous chondrites are intriguing and unique in the sense that they are the only rocks that provide pristine records of the early solar nebular processes. We report here results of a detailed mineralogical, chemical, amino acid and isotopic studies of a recently observed fall at Mukundpura, near Jaipur in Rajasthan, India. Abundance of olivines in this meteorite is low and of serpentine minerals is high. FeO/SiO_2 = 1.05 in its Poorly Characterized Phases(PCP) is similar to that observed in other CM2.0 chondrites. The water content of ～9.8 wt.% is similar to that found in many other CM chondrites.Microscopic examination of matrix shows that its terrestrial weathering grade is WO but aqueous parent body alteration is high, as reflected in low abundance of identifiable chondrules and abundant remnants of chondrules(～7%). Thus, most of the chondrules formed initially have been significantly altered or dissolved by aqueous alterations on their parent bodies. The measured bulk carbon(2.3%) and nitrogen content and their isotopic(δ¹³C =-5.5‰, δ¹⁵N = 23.6%0) composition is consistent with CM2.0 classification probably bordering CM1. Several amino acids such as Alanine, Serine, Proline, Valine, Threonine,Leucine, Isoleucine, Asparagine and Histamine are present. Tyrosine and Tryptophan may occur in trace amounts which could not be precisely determined. All these data show that Mukundpura chondrite lies at the boundary of CM2.0 and CM1 type carbonaceous chondrites making it one of the most primitive chondrites.  相似文献   

免疫多糖对栉孔扇贝酸性磷酸酶、碱性磷酸酶和超氧化物歧化酶活性的影响   总被引：23，自引：1，他引：23  

牟海津  江晓路  刘树青  管华诗 《中国海洋大学学报(自然科学版)》1999,(3)

在栉孔扇贝的血清、血细胞和肝脏提取液中均发现有酸性磷酸酶（ＡＣＰ）、碱性磷酸酶（ＡＬＰ）和超氧化物歧化酶（ＳＯＤ）活性,其中,ＡＣＰ和ＡＬＰ在肝脏中的活性最高。采用１．０％的虫草多糖或海藻多糖作为免疫药物,对栉孔扇贝进行注射刺激后,发现血清中的ＡＣＰ、ＡＬＰ和ＳＯＤ活性有显著提高,血细胞中的ＡＣＰ和ＳＯＤ活性也有所增加,而肝脏提取液的这三种酶活性的变化不很明显。研究认为这两种多糖具有增强栉孔扇贝免疫活性的作用,在水产养殖业中有一定的开发价值。  相似文献   

煤矿酸性矿井水主动式生物修复中铁的行为与归宿     

盛益之  王广才  刘莹  李广贺 《地学前缘》2018,25(4):299-306

酸性条件下Fe(II)的生物氧化过程可以被有效应用于煤矿酸性矿井水修复中,但是Fe行为与归宿的不确定性增加了应用难度。本研究通过对某煤矿酸性矿井水场地发生的生物地球化学过程进行监测,富集培养场地沉积物嗜酸微生物群落,进行室内恒化生物反应器连续流实验,探究微生物作用下Fe及其他金属离子的行为与归宿。研究表明,Fe的形态转化是场地和反应器中最主要的生物地球化学过程。当pH<2.7时,反应更倾向于产生溶解性Fe(III);当2.7相似文献   

Comment on: Mass Fractions of Forty‐Six Major and Trace Elements,Including Rare Earth Elements,in Sediment and Soil Reference Materials Used in Environmental Studies. Fiket et al. (2017), Geostandards and Geoanalytical Research, 41, 123–135     

Vibor Roje 《Geostandards and Geoanalytical Research》2019,43(2):317-327

This paper is intended to be a constructive discussion of Fiket et al. (2017, Geostandards and Geoanalytical Research , 41 , 123–135), who dealt with the determination of major, trace and rare earth elements in several sediment and soil certified reference materials. In the present author's view, the paper by Fiket et al. (2017) suffers from a lack of reference to several publications in which somewhat similar results had already been reported. The present contribution therefore provides a comparison of previously published results with those of Fiket et al. for the CRMs soil NCS DC 77302 (GBW 07410), stream sediment NCS DC 73309 (GBW 07311), marine sediments MESS‐3 and NCS DC 75301 (GBW 07314) and estuarine sediment IAEA‐405. It is argued that this fuller consideration (a) allows critical evaluation of the quality of the results presented by Fiket et al. and (b) highlights the advantages of their work. Finally, attention is drawn to the (possible or real) problems that can arise during simultaneous determination of multiple trace elements.  相似文献   

X射线荧光光谱法测定重晶石中的硫酸钡方法研究   总被引：1，自引：0，他引：1  

陈景伟  宋江涛  陈朝阳 《岩矿测试》2017,36(4):382-387

应用XRF可快速测定重晶石中钡元素的总量,但当测定硫酸钡含量时,由于样品中的碳酸钡计入钡量造成硫酸钡的测定结果不准确,铜、铅、锌等有色金属元素对熔样坩埚会造成损害,需要进行酸处理除去碳酸钡、铅等干扰。而样品经酸处理后不同样品的剩余量不同,造成熔剂与样品的比例不确定,也不能准确测定硫酸钡的含量,因此保证熔剂与样品比例一致是解决该问题的关键。本文优化了样品前处理、熔片制样和仪器工作条件,将一定量样品以10%盐酸和10%硝酸溶解,过滤除去碳酸钡、硫酸钙及铜、铅、锌等有色金属元素,未溶解样品在700℃下灼烧后以氧化铝补充到原取样量,实现了熔剂与样品比例一致,再以硝酸铵作氧化剂,溴化锂和碘化铵作脱模剂,1075℃熔融制片,即可用XRF准确测定硫酸钡的含量。本方法的相对标准偏差(RSD)小于0.4%,检出限为72μg/g,较ICP-OES等方法的检测周期短、干扰元素少,提高了测试效率和分析质量。  相似文献   

封闭压力酸溶-电感耦合等离子体质谱法同时测定电气石中29种元素   总被引：4，自引：4，他引：0  

成学海  夏传波  郑建业  张文娟  刘晶 《岩矿测试》2017,36(3):231-238

电气石是一种含硼的铝硅酸盐矿物,是重要的非金属矿产资源和成岩成矿作用的灵敏示踪剂,因类质同象置换普遍使其组成成分多变,主量元素为Si、B、Al、Fe和Mg,微量元素有稀土元素、Cu、Pb、Zn、Sn、Ag和Sr等。电气石的化学性质非常稳定,不能被一般的酸或碱完全溶解,本文采用硝酸-氢氟酸封闭压力溶矿,50%王水封闭压力复溶进行样品前处理,建立了电感耦合等离子体质谱法测定电气石中稀有轻金属、重金属、放射性金属、稀土元素等29种元素的分析方法。方法检出限为0.003~0.4μg/g,精密度(RSD,n=12)为0.9%~9.2%;国家标准物质的测定值与标准值基本相符,各元素的加标回收率为95%~105%。本方法解决了电气石样品难分解、复溶时易出现氢氧化铝微细残渣的问题,样品试液中B、Al、Fe等主要共存离子的干扰小,各待测元素测定结果准确、可靠。  相似文献   

涪陵页岩气田深层气井酸处理技术研究          下载免费PDF全文

张驰 《探矿工程》2017,44(12):30-33，58

涪陵页岩气田进入二期产建阶段,页岩气井埋深增加,压裂改造难度增大,尤其是在设备限压仅为93 MPa的前提下,深井施工压力高,酸降效果不明显,严重限制了后期各项改造措施的执行。通过分析深层页岩气井酸降效果降低的主要原因,并在此基础上通过室内及现场试验研究了影响酸处理效果的主要因素,试验表明：提高酸处理排量、增加酸液浓度、合理优化酸液用量将有助于提高酸处理效果,为涪陵页岩气田深层页岩气井后续的压裂施工提出了优化建议。  相似文献   

考虑非达西效应的酸蚀裂缝流场数值模拟     

郭建春  庄园  刘超 《岩土力学》2015,36(11):3315-3321

酸压改造后的酸蚀裂缝是储层流体的主要流动通道,研究流体在酸蚀裂缝中的流动规律是十分必要的。本文介绍了目前裂隙流动研究中的4种常用控制方程及各自的适用条件,确定了Navier-Stokes方程为酸蚀裂缝流场数值模拟的控制方程。为了分析酸蚀裂缝流场分布规律以及非达西效应对裂缝导流能力的影响,利用逆向工程技术对两种不同刻蚀形态的酸蚀岩样壁面进行了实体重构,并采用有限元数值模拟方法进行了不同流量下的酸蚀裂缝流动试验。结果表明：酸刻蚀形态和裂缝接触关系对流场分布的影响较大。隙宽分布平滑的均匀刻蚀裂缝,其流态稳定、曲折度低,但由于裂缝开度较窄且比表面较高,边界层效应明显,流体流动时产生的黏滞阻力较高;沟槽裂缝曲面粗糙,隙宽分布复杂,流体流动时流态不稳定,曲折度高,在高流量下会产生明显的涡流流动,增大惯性阻力。裂缝通道存在缩颈现象会引起流体绕流和多次加减速,产生额外的压力损耗。随着模拟流量的增大,压降与流量会逐渐偏离线性关系而呈现出非达西流动现象。酸蚀裂缝壁面越粗糙,产生非达西效应时的临界流量和临界雷诺数就越小,在相同流量下非达西效应就越强烈,导流能力下降速率更快。  相似文献   

无定形碳酸钙结合蛋白对鼠前成骨细胞MC3T3-E1碱性磷酸酶活性的影响     

万翔  孙娟  苏境坦  梁晓  张文权  郑桂兰  谢莉萍  王洪钟  张贵友  杜晓东  张荣庆 《广东海洋大学学报》2012,(3):13-18

以 MC3T3-E1细胞系为实验材料,探讨了真核表达的重组蛋白 rACCBP 对成骨细胞的作用.结果表明:rACCBP 对 MC3T3-E1的分化具有抑制作用,用含有0.001 g/mL rACCBP 的 DMEM 培养液,培养8 d 后细胞的ALP 活性仅为7.187 U/mg,远低于参照的11.917 U/mg; rACCBP 削弱了 dexamethane 和 ascorbic acid 对 MC3T3-E1的诱导作用  相似文献   

Chemical and spectroscopic characterization of dissolved humic substances in a mangrove-fringed estuary in the eastern coast of Hainan Island, China   总被引：1，自引：0，他引：1  

张耀玲  杜金洲  彭浡  张芬芬  赵欣  张经 《中国海洋湖沼学报》2013,31(2):454-463

Mangrove-derived dissolved organic matter(DOM) has an important effect on estuarine and coastal area on a large scale.In order to improve the understanding of origin,composition,and fate of DOM in mangrove-fringed estuarine and coastal areas,dissolved humic substances(DHS) were isolated from one mangrove pore-water sample and one near-shore seawater sample downstream the mangrove pore-water site in the eastern coast of Hainan Island,South China.Fulvic acids,humic acids and XAD-4 fractions were obtained from the two water samples by using a two-column array of XAD-8 and XAD-4 resins.Chemical and spectroscopic methods were used to analyze the features of these DHS.Compared to the mangrove pore-water DHS,the near-shore seawater DHS were found rich in 13 C with lower C/N ratios and more aliphatic compounds and carbohydrates,but less aromatic structures and carboxyl groups.As for the three fractions of the two DHS,XAD-4 fractions contain more aliphatics,carbohydrates,carboxyl groups,and enrich in 13 C with respect to both fulvic and humic acids.Photo-oxidation transformation and contribution from marine-derived DOM were considered as the main reasons resulted in the difference in compositional features for these DHS in this study.  相似文献